Electrooxidation of pyrrole-terminated self-assembled lipoic acid derivatives

JF Cabrita, AS Viana, C Eberle, FP Montforts… - Surface science, 2009 - Elsevier
New pyrrole derivatives, pyrrolyl lipoic acid (Py-LA 3) and dipyrrolyl lipoic acid (Py2-LA 2)
have been used for surface attachment and immobilisation on gold surfaces, by self-
assembly. The electrooxidation of the surface-confined pyrroles was analysed by cyclic
voltammetry and the modified electrodes morphological and thickness changes addressed
by scanning probe microscopy and ellipsometry. The data support the formation of
oligomers as a result of the pendant-pyrrolyl units ease oxidation but provide no evidence of …
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