Energy, entropy and the reaction coordinate: thermodynamic-like relations in chemical kinetics
A simple thermodynamic-like interpretation of the relation between the kinetic and the
thermodynamic parameters of chemical reactions (“linear free energy relations”) is
discussed and applied. The central concept is the introduction of mixing (or configurational)
entropy to account for the activation barrier of chemical reactions.
thermodynamic parameters of chemical reactions (“linear free energy relations”) is
discussed and applied. The central concept is the introduction of mixing (or configurational)
entropy to account for the activation barrier of chemical reactions.
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