Exciton relaxation processes in colloidal core/shell ZnSe/ZnS nanocrystals

M Lomascolo, A Cretı̀, G Leo, L Vasanelli… - Applied Physics …, 2003 - pubs.aip.org
Colloidal ZnSe nanocrystals are coated with a ZnS shell and are investigated by means of
time-resolved photoluminescence spectroscopy. These nanocrystals are stable against
photooxidation and have photoluminescence quantum efficiencies around 15% even
months after the synthesis. Recombination processes are investigated as a function of the
excitation intensity and the emission energy. Nonlinear processes such as Auger
recombination dominate in the early times after the photogeneration of electron-hole pairs …
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