Facial and meridional [N C N]− intramolecular coordination systems: structure of fac-PtBrMe2 {2, 6-(pzCH2) 2C6H3}· 1/2C6H6 {[2, 6-(pzCH2) 2C6H3]−= 2, 6-(bis …

AJ Canty, J Patel, BW Skelton, AH White - Journal of Organometallic …, 2000 - Elsevier
Intramolecular coordination by the six-membered monoanionic N, C, N chelating system 2, 6-
(pyrazol-1-ylmethyl) phenyl and substituted derivatives can give rise to facial and meridional
coordination, exhibited by structural studies of facial coordination in the platinum (IV)
complex PtBrMe2 {2, 6-(pzCH2) 2C6H3}· 1/2C6H6 and meridional coordination in the
platinum (II) complex PtBr {2, 6-(3, 5-Me2pzCH2) 2C6H3} showing close to 'ideal'geometry
for the [N C N]− donor sets. A platinum (IV) complex is formed by oxidative addition of 2, 6 …
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