Ferroelectricity in rare-earth modified Hafnia thin films deposited by sequential pulsed laser deposition

Y Sharma, D Barrionuevo, R Agarwal… - ECS Solid State …, 2015 - iopscience.iop.org
ECS Solid State Letters, 2015iopscience.iop.org
Room temperature ferroelectricity in pulsed laser deposited rare-earth doped hafnium oxide
(HfO 2) thin films is discussed. Maximum values of remnant polarizations (P r)∼ 13.5 and 12
μC/cm 2 along with coercive fields (EC)∼ 334 and 384 kV/cm are observed in 6 mol.% of
rare-earth (Sm or Gd) doped-HfO 2 thin films (Sm: HfO 2 and Gd: HfO 2), respectively.
Piezoresponse force microscopy measurements confirmed ferroelectric nature of films by
showing phase hysteresis and butterfly amplitude loops. It is noticed that wake-up cycles …
Abstract
Room temperature ferroelectricity in pulsed laser deposited rare-earth doped hafnium oxide (HfO 2) thin films is discussed. Maximum values of remnant polarizations (P r)∼ 13.5 and 12 μC/cm 2 along with coercive fields (E C)∼ 334 and 384 kV/cm are observed in 6 mol.% of rare-earth (Sm or Gd) doped-HfO 2 thin films (Sm: HfO 2 and Gd: HfO 2), respectively. Piezoresponse force microscopy measurements confirmed ferroelectric nature of films by showing phase hysteresis and butterfly amplitude loops. It is noticed that wake-up cycles improved the remnant polarization and found to be necessary for the forming of well saturated hysteresis loops. Our results showed potential toward realization of future highly scaled non-volatile ferroelectric memories.
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