Field-theoretic simulations of confined polymer solutions

A Alexander-Katz, AG Moreira… - The Journal of chemical …, 2003 - pubs.aip.org
We used field-theoretic simulations to study the equilibrium behavior of a polymer solution
under good solvent conditions confined to a slit of width L. In particular, we obtained the
chemical potential and the density profiles across the slit for different values of the monomer
excluded volume over a wide range of concentrations C. We also obtained mean field
results for the chemical potential and the density profiles. The effective correlation length ξ
eff was calculated from the density profiles and compared to the mean field result (valid in …
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