Flow dynamics of concentrated starlike micelles: A superposition rheometry investigation into relaxation mechanisms

AR Jacob, AS Poulos, AN Semenov, J Vermant… - Journal of …, 2019 - pubs.aip.org
The steady state flow of a concentrated dispersion of starlike micelles above the colloidal
glass transition concentration is interrogated by superimposing a small amplitude straining
motion orthogonal to the main flow direction. Strain amplitude sweeps reveal that the linear
response region of the orthogonal perturbation increases with increasing flow rate,
consistent with a fluidization of the materials. Orthogonal dynamic frequency sweeps
(ODFSs) are obtained for a wide range of shear rates probing the full flow curve. The shear …
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