Formal total synthesis of (−)-balanol: a potent PKC inhibitor
S Yaragorla, R Muthyala - Tetrahedron Letters, 2010 - Elsevier
An efficient formal total synthesis of the PKC inhibitor balanol 1 is described, starting from
the commercially available pentane1, 5-diol. A Shi epoxidation and Pd (0)-mediated
nitrogen substitution with double inversion established the correct configuration of the
balanol precursor 3.
the commercially available pentane1, 5-diol. A Shi epoxidation and Pd (0)-mediated
nitrogen substitution with double inversion established the correct configuration of the
balanol precursor 3.
[引用][C] Formal total synthesis of ())-balanol: a potent PKC inhibitor pp 467–470
S Yaragorla, R Muthyala - Tetrahedron Letters, 2010
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