From easily oxidized to easily reduced thiophene‐based materials

G Barbarella, L Favaretto, M Zambianchi… - Advanced …, 1998 - Wiley Online Library
G Barbarella, L Favaretto, M Zambianchi, O Pudova, C Arbizzani, A Bongini…
Advanced Materials, 1998Wiley Online Library
Thiophene‐based materials for n‐type semiconductor devices? A new strategy towards this
goal that consists of chemically transforming the thienyl sulfurs into the corresponding S, S‐
dioxides (see Figure) is described. This is shown—for quarter‐and quinquethiophenes—to
lead to very stable oligomers with increased electron delocalization and electron affinity.
Thiophene‐based materials for n‐type semiconductor devices? A new strategy towards this goal that consists of chemically transforming the thienyl sulfurs into the corresponding S,S‐dioxides (see Figure) is described. This is shown—for quarter‐ and quinquethiophenes—to lead to very stable oligomers with increased electron delocalization and electron affinity.
Wiley Online Library
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