Heterogeneous dynamics, correlated time and length scales in ionic deep eutectics: Anion and temperature dependence

S Banerjee, PK Ghorai, S Das, J Rajbangshi… - The Journal of …, 2020 - pubs.aip.org
Heterogeneous relaxation dynamics often characterizes deep eutectic solvents. Extensive
and molecular dynamics simulations have been carried out in the temperature range, 303≤
T/K≤ 370, for studying the anion and temperature dependencies of heterogeneous
dynamics of three different ionic acetamide deep eutectics: acetamide+ LiX, X being
bromide (Br−), nitrate (⁠ NO 3−⁠), and perchlorate (⁠ ClO 4−⁠). These systems are chosen
because the fractional viscosity dependence of average relaxation rates reported by various …

[PDF][PDF] Heterogeneous Dynamics, Correlated Time and Length Scales in Ionic Deep Eutectics: Anion and Temperature Dependence

PKG Swarup Banerjee, S Das, J Rajbangshi, R Biswas - researchgate.net
Heterogeneous relaxation dynamics often characterizes deep eutectic solvents. Extensive
and molecular dynamics simulations have been carried out in the temperature range, 303≤
𝑇 𝐾≤ 370⁄, for studying the anion and temperature dependencies of heterogeneous
dynamics of three different ionic acetamide deep eutectics: acetamide+ LiX, X being
bromide (𝐵𝑟−), nitrate (𝑁𝑂3−) and perchlorate (𝐶𝑙𝑂4−). These systems are chosen
because fractional viscosity dependence of average relaxation rates reported by various …
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