complexes towards the hydrosilylation of aldehydes. These catalysts incorporate a bulky
diazabutadiene ligand and exhibit good functional group tolerance and chemoselectivity in
the hydrosilylation of aldehydes, utilizing primary silanes as the reducing agent. The
reactions proceed with turnover frequencies approaching 150 h− 1 in some instances,
similar to those observed for other manganese-based catalysts. The conversion of aromatic …