Impact of iodide substitution on the physical properties and stability of cesium lead halide perovskite thin films CsPbBr3− xIx (0≤ x≤ 1)

L Atourki, E Vega, M Mollar, B Marí, H Kirou… - Journal of Alloys and …, 2017 - Elsevier
L Atourki, E Vega, M Mollar, B Marí, H Kirou, K Bouabid, A Ihlal
Journal of Alloys and Compounds, 2017Elsevier
This study sheds light on the effect of iodide substitution on the structural and optical
properties of solution processed mixed cesium lead perovskite thin films CsPbBr 3− x I x
(0≤ x≤ 1) as well as their atmospheric and thermal stability. Pawley fit indicated that the
mixed lead halide CsPbBr 3− x I x perovskite crystallizes in the orthorhombic (Pnma) space
group. X-ray diffraction analyses showed a shift to lower angles when the average fraction of
iodide incorporated increased indicating the expansion of the lattice. Absorbance …
Abstract
This study sheds light on the effect of iodide substitution on the structural and optical properties of solution processed mixed cesium lead perovskite thin films CsPbBr3−xIx (0 ≤ x ≤ 1) as well as their atmospheric and thermal stability. Pawley fit indicated that the mixed lead halide CsPbBr3−xIx perovskite crystallizes in the orthorhombic (Pnma) space group. X-ray diffraction analyses showed a shift to lower angles when the average fraction of iodide incorporated increased indicating the expansion of the lattice. Absorbance measurements show that the CsPbBr3−xIx films exhibit a very high absorbance in the visible and short infrared region. The band gap of CsPbBr3−xIx is tuned from 2.38 (CsPbBr3) to 2.17 eV (CsPbBr2I1) following the Vegard's law. CsPbBr3 films showed a bright photoluminescence with emission maximum at 530 nm CsPbBr3−xIx films demonstrate excellent stability after aging for two days in a humid environment (relative humidity of ∼60%) and under thermal annealing at relatively high temperature.
Elsevier
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