In situ generated carbon nanosheet-covered micron-sized porous Si composite for long-cycling life lithium-ion batteries

W Luo, C Fang, X Zhang, J Liu, H Ma… - ACS Applied Energy …, 2020 - ACS Publications
W Luo, C Fang, X Zhang, J Liu, H Ma, G Zhang, Z Liu, X Li
ACS Applied Energy Materials, 2020ACS Publications
Micron-sized silicon-based materials have attracted immense attention for large-scale
lithium-ion batteries (LIBs) owing to high theoretical capacity and low cost. However, it is
limited by severe volume expansion and fast capacity fading in a cycling process. Here, we
proposed a facile strategy to obtain an in situ formed carbon nanosheet template-covered
micron-sized porous silicon composite (PSi@ CNS) from the low-cost Al–Si alloy and
bicontinuous C6H12O6/SiO2 structural layer. The templated assembly of the inner …
Micron-sized silicon-based materials have attracted immense attention for large-scale lithium-ion batteries (LIBs) owing to high theoretical capacity and low cost. However, it is limited by severe volume expansion and fast capacity fading in a cycling process. Here, we proposed a facile strategy to obtain an in situ formed carbon nanosheet template-covered micron-sized porous silicon composite (PSi@CNS) from the low-cost Al–Si alloy and bicontinuous C6H12O6/SiO2 structural layer. The templated assembly of the inner distributed PSi and outer in situ generated CNS can form a stable and controllable conductive structure with an increased specific surface area and enhanced intermolecular interactions. This unique composite structure results in a significant increase of electrolyte transfer and long-term stability. As an anode material for LIBs, the PSi@CNS composite exhibits a high reversible capacity of 1272 mA h g–1 at 1 A g–1 after 500 cycles in the micron-sized PSi/C composite system. This work provides a templated idea for long-term stable LIBs.
ACS Publications
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