Incorporation of γ-butyrolactone (GBL) dramatically lowers the phase transition temperature of formamidinium-based metal halide perovskites

S Ruan, R Fan, N Pai, J Lu, NAS Webster… - Chemical …, 2019 - pubs.rsc.org
Chemical Communications, 2019pubs.rsc.org
We demonstrate that the δ to α phase transition temperature of formamidinium-based
perovskites is reduced by∼ 50° C through the incorporation of∼ 2 wt% γ-butyrolactone
(GBL) into the crystal lattice. The intercalation of GBL is found to expand the unit cell of the δ-
phase, reducing the energy barrier for thermal conversion.
We demonstrate that the δ to α phase transition temperature of formamidinium-based perovskites is reduced by ∼50 °C through the incorporation of ∼2 wt% γ-butyrolactone (GBL) into the crystal lattice. The intercalation of GBL is found to expand the unit cell of the δ-phase, reducing the energy barrier for thermal conversion.
The Royal Society of Chemistry
以上显示的是最相近的搜索结果。 查看全部搜索结果