Interaction of metal ions with N-glycosylamines: isolation and characterization of the products of 4, 6-O-benzylidene-N-(o-carboxyphenyl)-β-d-glucopyranosylamine …

TM Das, CP Rao, E Kolehmainen - Carbohydrate Research, 2001 - Elsevier
Metal-ion complexes of Li+, Na+, K+, Mg2+, Ca2+, Ba2+, Pb2+, Cd2+, Hg2+ with 4, 6-O-
benzylidene-N-(o-carboxyphenyl)-β-d-glucopyranosylamine were synthesized and isolated
as solid products and characterized by analytical means as well as by spectral techniques,
such as, 1H and 13C NMR, FTIR, absorption, FAB mass spectrometry, optical rotation and
CD. While the alkali metal ions formed ML type of complexes, the other metal ions formed
ML2 type complexes. Molecular weights of the complexes of Li+, Na+ and K+ were …
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