Intrinsic size parameters for palmitoylated and carboxyamidomethylated peptides
Cross sections for 61 palmitoylated peptides and 73 cysteine-unmodified peptides are
determined and used together with a previously obtained tryptic peptide library to derive a
set of intrinsic size parameters (ISPs) for the palmitoyl (Pal) group (1.26±0.04),
carboxyamidomethyl (Am) group (0.92±0.04), and the 20 amino acid residues to assess the
influence of Pal-and Am-modification on cysteine and other amino acid residues. These
values highlight the influence of the intrinsic hydrophobic and hydrophilic nature of these …
determined and used together with a previously obtained tryptic peptide library to derive a
set of intrinsic size parameters (ISPs) for the palmitoyl (Pal) group (1.26±0.04),
carboxyamidomethyl (Am) group (0.92±0.04), and the 20 amino acid residues to assess the
influence of Pal-and Am-modification on cysteine and other amino acid residues. These
values highlight the influence of the intrinsic hydrophobic and hydrophilic nature of these …
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