[PDF][PDF] Investigation of reactive intermediates of chemical reactions in solution by electrospray ionization mass spectrometry: Radical cation chain reactions
S Meyer, R Koch, JO Metzger - Angewandte …, 2003 - metzger.chemie.uni-oldenburg.de
Transient radicals tracked down: An electrospray ionization mass spectrometer coupled on-
line to a microreactor system is useful for investigating reactions in solution and for directly
detecting reactive intermediates. The transient radical cations 1C+ and 2C+ formed in the
radical cation chain dimerization of trans-anethole were detected unambiguously by MS/MS
methods.
line to a microreactor system is useful for investigating reactions in solution and for directly
detecting reactive intermediates. The transient radical cations 1C+ and 2C+ formed in the
radical cation chain dimerization of trans-anethole were detected unambiguously by MS/MS
methods.
[PDF][PDF] Investigation of reactive intermediates of chemical reactions in solution by electrospray ionization mass spectrometry: radical chain reactions
J Griep-Raming, S Meyer… - Angewandte …, 2002 - metzger.chemie.uni-oldenburg.de
The reaction mechanism is the detailed, step-by-step description of a chemical reaction.
Most chemical reactions take place through a complex sequence of steps via reactive
intermediates. The most important reactive intermediates in organic chemical reactions in
solution are carbocations, carbanions, carbenes, and radicals. Of course, chemists have
been able to detect these intermediates indirectly by chemical and physical methods, and
spectroscopic methods are available to study them directly and in detail.[1] For example …
Most chemical reactions take place through a complex sequence of steps via reactive
intermediates. The most important reactive intermediates in organic chemical reactions in
solution are carbocations, carbanions, carbenes, and radicals. Of course, chemists have
been able to detect these intermediates indirectly by chemical and physical methods, and
spectroscopic methods are available to study them directly and in detail.[1] For example …