Iron-catalyzed oxidation of tertiary amines: Synthesis of β-1, 3-dicarbonyl aldehydes by three-component C–C couplings
β-1, 3-Dicarbonyl aldehydes were synthesized by iron-catalyzed oxidative reactions
between 1, 3-dicarbonyl compounds and two molecules of tertiary amines in the presence of
tert-butyl hydroperoxide (TBHP). α, β-Unsaturated aldehydes generated by tertiary amine
oxidation in situ act as key intermediates under mild reaction conditions.
between 1, 3-dicarbonyl compounds and two molecules of tertiary amines in the presence of
tert-butyl hydroperoxide (TBHP). α, β-Unsaturated aldehydes generated by tertiary amine
oxidation in situ act as key intermediates under mild reaction conditions.
β-1,3-Dicarbonyl aldehydes were synthesized by iron-catalyzed oxidative reactions between 1,3-dicarbonyl compounds and two molecules of tertiary amines in the presence of tert-butyl hydroperoxide (TBHP). α,β-Unsaturated aldehydes generated by tertiary amine oxidation in situ act as key intermediates under mild reaction conditions.
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