Laser writing of CsPbBr3 nanocrystals mediated by closely-packed Au nanoislands

W Zhuang, S Li, F Deng, G Li, S Tie, S Lan - Applied Surface Science, 2021 - Elsevier
W Zhuang, S Li, F Deng, G Li, S Tie, S Lan
Applied Surface Science, 2021Elsevier
Metal halide perovskites have attracted great interest in recent years owing to their excellent
luminescence properties. The low formation energy makes it possible to synthesize
perovskites of different types via direct laser writing. Here, we report on the formation of
metal halide perovskite (CsPbBr 3) nanocrystals coupled to the surface plasmon
resonances of gold (Au) nanoparticles by irradiating a polymer film doped with the
precursors (CsBr and PbBr 3) and coated on a thin Au film. The Au film, which is composed …
Abstract
Metal halide perovskites have attracted great interest in recent years owing to their excellent luminescence properties. The low formation energy makes it possible to synthesize perovskites of different types via direct laser writing. Here, we report on the formation of metal halide perovskite (CsPbBr3) nanocrystals coupled to the surface plasmon resonances of gold (Au) nanoparticles by irradiating a polymer film doped with the precursors (CsBr and PbBr3) and coated on a thin Au film. The Au film, which is composed of closely-packed Au nanoislands deposited on a silica substrate, act as not only the absorber of 800-nm femtosecond laser pulses but also the heat source for synthesizing and annealing of CsPbBr3 nanocrystals. The formation of CsPbBr3 nanocrystals in the area of laser irradiation was confirmed by Raman scattering spectra measurements. In addition, closely-packed Au nanoislands are transformed into isolated Au nanoparticles which exhibit surface plasmon resonances at ~530 nm. The CsPbBr3 nanocrystals coupled to isolated Au nanoparticles emit two-photon-induced luminescence at ~513 nm, which is enhanced by the surface plasmon resonances through the Purcell effect. An optimal laser power for direct laser writing was determined and the decomposition of CsPbBr3 nanocrystals was observed if a large laser power was employed. Our results indicate the possibility for the formation and annealing of perovskite nanocrystals coupled to surface plasmon resonances by one-step laser writing and open new horizon for their practical applications in color display and optical memory.
Elsevier
以上显示的是最相近的搜索结果。 查看全部搜索结果

Google学术搜索按钮

example.edu/paper.pdf
搜索
获取 PDF 文件
引用
References