This paper reports on a rare magmatic suite of adakitic rocks and associated magnesian and potassium-rich magmatic enclaves and dikes, which occur in the Tunchang–Fengmu area, Hainan Island (Southeast China). LA-ICP‐MS zircon U–Pb age data show that they were generated in the late Early Cretaceous (~107Ma). The adakitic rocks, consisting mainly of granodiorites and biotite granites, are high-K calc-alkaline and have low Mg^# values (0.27–0.50). They are geochemically similar to slab-derived adakites, e.g., with high SiO₂, Al₂O₃, Sr, Sr/Y and La/Yb values, low Y and Yb contents, and negligible Eu and positive Sr anomalies. They also have relatively uniform (⁸⁷Sr/⁸⁶Sr)_i (0.7086–0.7096), (²⁰⁶Pb/²⁰⁴Pb)_i (18.50–18.61), (²⁰⁷Pb/²⁰⁴Pb)_i (15.56–15.64) and (²⁰⁸Pb/²⁰⁴Pb)_i (38.17–38.44) isotope ratios, with slightly variable ε_Nd(t) (−3.85 to −6.55) and zircon in situ ε_Hf(t) (−4.7 to +1.7) values. The mafic enclaves and dikes display disequilibrium textures (e.g., multiple-zoned clinopyroxene with low-MgO rims in contact with perthite and quartz microcrystals). They are high-K calc-alkaline and shoshonitic, and all but one sample have high Mg^# (0.63–0.72) values. These mafic rocks are characterized by light rare earth element enrichment and heavy rare earth element (REE) depletion, negligible Eu and Sr and positive Pb anomalies, and Nb and Ta depletion. They have slightly more variable initial ⁸⁷Sr/⁸⁶Sr isotope ratios (0.7064–0.7086), ε_Nd(t) (−5.1 to +0.1) values, and (²⁰⁶Pb/²⁰⁴Pb)_i (18.35–18.50), (²⁰⁷Pb/²⁰⁴Pb)_i (15.45–15.59) and (²⁰⁸Pb/²⁰⁴Pb)_i (38.18–38.70) ratios. One mafic dike sample has zircon in situ ε_Hf(t) values (−4.94 to −2.42) similar to those of adakitic rocks (−4.7 to +1.7) in the area. We suggest that the adakitic rocks were most likely generated by partial melting of newly underplated basaltic lower crust with arc-like geochemical characteristics, and the primitive compositions of the mafic enclaves and dikes likely originated from lithospheric+asthenospheric mantle sources metasomatized by subducted oceanic sediments or a relatively juvenile lithospheric mantle source. Mantle-derived primitive magmas likely underwent mixing at depth with minor crustally-derived felsic magmas before being injected into the adakitic magma chamber. Such injections may have broken up the magma into discrete globules and convective motion distributed the enclaves through the adakitic host. Asthenosphere upwelling due to the roll-back of the subducted Paleo-Pacific plate likely triggered the coeval late Early Cretaceous crust- and mantle-derived magmatism, resulting in the magma hybridization observed on Hainan Island.