Magnetic and conventional shape memory behavior of Mn–Ni–Sn and Mn–Ni–Sn (Fe) alloys

AS Turabi, P Lázpita, M Sasmaz… - Journal of Physics D …, 2016 - iopscience.iop.org
Journal of Physics D: Applied Physics, 2016iopscience.iop.org
Magnetic and conventional shape memory properties of Mn 49 Ni 42 Sn 9 (at.%) and Mn 49
Ni 39 Sn 9 Fe 3 (at.%) polycrystalline alloys exhibiting martensitic transformation from
ferromagnetic austenite into weakly magnetic martensite are characterized under
compressive stress and magnetic field. Magnetization difference between transforming
phases drastically increases, while transformation temperature decreases with the addition
of Fe. Both Mn 49 Ni 42 Sn 9 and Mn 49 Ni 39 Sn 9 Fe 3 alloys show remarkable …
Abstract
Magnetic and conventional shape memory properties of Mn 49 Ni 42 Sn 9 (at.%) and Mn 49 Ni 39 Sn 9 Fe 3 (at.%) polycrystalline alloys exhibiting martensitic transformation from ferromagnetic austenite into weakly magnetic martensite are characterized under compressive stress and magnetic field. Magnetization difference between transforming phases drastically increases, while transformation temperature decreases with the addition of Fe. Both Mn 49 Ni 42 Sn 9 and Mn 49 Ni 39 Sn 9 Fe 3 alloys show remarkable superelastic and shape memory properties with recoverable strain of 4% and 3.5% under compression at room temperature, respectively. These characteristics can be counted as extraordinary among the polycrystalline NiMn-based magnetic shape memory alloys. Critical stress for phase transformation was increased by 34 MPa in Mn 49 Ni 39 Sn 9 Fe 3 and 21 MPa in Mn 49 Ni 42 Sn 9 at 9 T, which can be qualitatively understood in terms of thermodynamic Clausius–Clapeyron relationships and in the framework of the suggested physical concept of a volume magnetostress.
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