Magnetism and the Verwey transition in under pressure

S Klotz, G Steinle-Neumann, T Strässle, J Philippe… - Physical Review B …, 2008 - APS
S Klotz, G Steinle-Neumann, T Strässle, J Philippe, T Hansen, MJ Wenzel
Physical Review B—Condensed Matter and Materials Physics, 2008APS
We have used high precision neutron diffraction and ab initio calculations to investigate the
behavior of the magnetism of spinel magnetite (Fe 3 O 4) under pressure in the 0–10 GPa
range and at temperatures of 130–300 K. We find a significant but continuous decrease of
the magnetic moments at both the A and B sites to at least 10 GPa, as well as an absence of
any detectable pressure dependence of the oxygen atomic parameter. The data indicate a
very weak dependence of the saturation moment on pressure and temperature and rule out …
We have used high precision neutron diffraction and ab initio calculations to investigate the behavior of the magnetism of spinel magnetite under pressure in the range and at temperatures of . We find a significant but continuous decrease of the magnetic moments at both the and sites to at least , as well as an absence of any detectable pressure dependence of the oxygen atomic parameter. The data indicate a very weak dependence of the saturation moment on pressure and temperature and rule out unambiguously a transition from inverse to normal spinel in the range investigated. Consequently, charge ordering cannot be precluded as the origin of the Verwey transition under pressure.
American Physical Society
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