Mechanistic investigations on the competition between the cyclopolymerization and [2+ 2+ 2] cycloaddition of 1, 6-heptadiyne derivatives using second-generation …
Until recently, the cyclopolymerization (CP) of 1, 6-heptadiyne derivatives using Grubbs
catalysts had been unsuccessful, leading to the misbelief that these catalysts were inactive
in these circumstances. However, a recent breakthrough has changed this previous
perspective of CP, where a successful living CP was reported using a third-generation
Grubbs catalyst with the aid of weakly coordinating ligands. Although it became clear that
weakly coordinating ligands greatly enhanced the efficiency of CP by suppressing the …
catalysts had been unsuccessful, leading to the misbelief that these catalysts were inactive
in these circumstances. However, a recent breakthrough has changed this previous
perspective of CP, where a successful living CP was reported using a third-generation
Grubbs catalyst with the aid of weakly coordinating ligands. Although it became clear that
weakly coordinating ligands greatly enhanced the efficiency of CP by suppressing the …
[引用][C] Mechanistic Investigations on the Competition between the Cyclopolymerization and [2+ 2+ 2] Cycloaddition of 1, 6-Heptadiyne Derivatives Using Second …
K Eun-Hye, K Cheol, Y Sanghee, O Elina, C Tae-Lim - 2016
以上显示的是最相近的搜索结果。 查看全部搜索结果