Chemistry of metalated container molecules

B Kersting, U Lehmann - Advances in Inorganic Chemistry, 2009 - Elsevier
Metalated Container Molecules: Host Systems and Complex Types Metalated container
molecules can … metal coordination sites anchored within or next to a molecular cavity (Fig. 2). A …

Metalated container molecules

B Kersting - Zeitschrift für anorganische und allgemeine …, 2004 - Wiley Online Library
The coordination chemistry of metalated container molecules is currently attracting much
interest, because the properties of such compounds are often different from those of their …

Realization of Unusual Ligand Binding Motifs in Metalated Container Molecules: Synthesis, Structures, and Magnetic Properties of the Complexes [(LMe) Ni2 (μ‐L′)] …

J Hausmann, MH Klingele, V Lozan… - … A European Journal, 2004 - Wiley Online Library
… , to activate and transform small molecules,6 or to stabilize reactive intermediates.7 Such
compounds also allow an interplay of molecular recognition and transition-metal catalysis,8, 9 …

Installation of Copper (I) and Silver (I) Sites into TREN-Based Porous Organic Cages via Postsynthetic Metalation

HA Silva, BS Whitehead, CD Hastings, CK Tiwari… - …, 2024 - ACS Publications
… reported for molecular porous materials. In this report, we demonstrate postsynthetic metalation
of … The effect of metalation on the gas sorption properties of these molecular materials is …

Metallated Container Molecules: A Capsular Nickel Catalyst for Enhanced Butadiene Polymerisation

F Elaieb, S Sameni, M Awada… - European Journal of …, 2019 - Wiley Online Library
… The design and synthesis of new molecular catalysts … of functional synthons, some of them
metalated, which readily self-… the difficulty in synthesising container molecules with convergent …

Host-guest complexation. 47. Carcerands and carcaplexes, the first closed molecular container compounds

DJ Cram, S Karbach, YH Kim… - Journal of the …, 1988 - ACS Publications
Abstract: Thedesign, synthesis, and properties are reported for the first carcerand (1), a
closed-surface container compound in whose interior are trapped simple organic molecules, a …

Selective anion encapsulation by a metalated cryptophane with a π-acidic interior

RM Fairchild, KT Holman - Journal of the American Chemical …, 2005 - ACS Publications
Metalation of the exterior arene faces of the molecular … of these anions by the metalated
cryptophane. H and 19 F NMR … examples of so-called molecular containers, 10 displaying an …

Assembly of trigonal and tetragonal prismatic cages from octahedral metal ions and a flexible molecular clip

ZM Liu, Y Liu, SR Zheng, ZQ Yu, M Pan… - Inorganic …, 2007 - ACS Publications
… clip and two blocked octahedral centers with lowered symmetry afforded metalated … of
encapsulating small molecules. Self-assembly of metalated container molecules by utilizing …

cis‐Bromination of Encapsulated Alkenes

G Steinfeld, V Lozan, B Kersting - … Chemie International Edition, 2003 - Wiley Online Library
Metalated container molecules are currently attracting much interest, since their properties
are often different from those of their constituent components. – 3 Several groups have …

A Regulable Internal Cavity inside a Resorcinarene‐Based Hemicarcerand

K Harada, R Sekiya, T Haino - Chemistry–A European Journal, 2020 - Wiley Online Library
… and metalation. The reversible size change of the capsule enables switching of its molecular
recognition … These container molecules have confined spaces capable of hosting small …