… iron-based catalyst such as inorganic salts or iron-containing … for catalysing the carbene
transfer/insertion reaction in … activity and enantioselectivity in comparison of iron catalyst. It was …

… by enzymes of the iron-containing cytochromes P450 (CYPs… catalysts. Thus, these engineered
P411s provided a new solution to enantioselective C–H insertion using acceptor carbenes…

… made using iron catalysts to perform CH functionalization … In nature, iron-containing enzymes
play an important role, eg… reported on an enantioselective CH functionalization of indole …

… on the involved catalytic system, the carbene insertion can … (diastereo- and enantioselectivity)
of the process. In order to … rhodium-based catalysts with iron-containing systems, which …

… iron containing enzyme based on cytochrome P450 monooxygenase. This enzyme is known
to nature because it promotes the direct insertion of oxygen into C–H … the catalytic carbene …

… This leads to lower TONs for RuMb compared to the iron-containing analogues. Strategies
… more arduous syntheses and still exhibit lower enantioselectivity compared to enzymes. (27-…

… catalysts, have only been reported with azides in amination reactions.To the best of our
knowledge these catalysts have not been reported in C—H insertion … The natural iron containing …

… carbene in developing heme-based C−H insertion catalysts … of IPCs and other iron-containing
biocatalysts,7 here we … with experimentally found non-enantioselective reaction.1m Their …

… asymmetric oxidation and asymmetric carbene or nitrene transfer reactions, but there are still
challenges in catalytic performance and new catalytic … or iron-containing cytochromes P450…

… high chemoselectivity, enantioselectivity, diastereoselectivity, … that we studied for carbene
insertion into C–H bonds (see section … has created iron-containing enzymes that catalyze C–H …