Mild Electrochemical Deprotection of N‐Phenylsulfonyl N‐Substituted Amines Derived from (R)‐Phenylglycinol
V Coeffard, C Thobie‐Gautier, I Beaudet, E Le Grognec… - 2008 - Wiley Online Library
V Coeffard, C Thobie‐Gautier, I Beaudet, E Le Grognec, JP Quintard
2008•Wiley Online LibraryThe electrochemical reduction of N‐phenylsulfonyl N‐substituted amines in a protic medium
under constant cathodic potential was found to be a mild desulfonylation method, which is
able to challenge the chemical ones. The influence of the nature of the N‐substituents was
considered in order to clarify the mechanistic aspects and to evaluate the scope of the
method.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
under constant cathodic potential was found to be a mild desulfonylation method, which is
able to challenge the chemical ones. The influence of the nature of the N‐substituents was
considered in order to clarify the mechanistic aspects and to evaluate the scope of the
method.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
Abstract
The electrochemical reduction of N‐phenylsulfonyl N‐substituted amines in a protic medium under constant cathodic potential was found to be a mild desulfonylation method, which is able to challenge the chemical ones. The influence of the nature of the N‐substituents was considered in order to clarify the mechanistic aspects and to evaluate the scope of the method.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
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