Mirror symmetry breaking and chiral amplification in foldamer-based supramolecular helical aggregates

S Azeroual, J Surprenant, TD Lazzara… - Chemical …, 2012 - pubs.rsc.org
S Azeroual, J Surprenant, TD Lazzara, M Kocun, Y Tao, LA Cuccia, JM Lehn
Chemical Communications, 2012pubs.rsc.org
Spontaneous asymmetric generation of supramolecular chiral fibers was observed in the
folding induced self-assembly of a lock-washer shaped foldamer. A secondary nucleation
growth mechanism is proposed to explain the observed chiral amplification or
deracemization of these supramolecular fibers.
Spontaneous asymmetric generation of supramolecular chiral fibers was observed in the folding induced self-assembly of a lock-washer shaped foldamer. A secondary nucleation growth mechanism is proposed to explain the observed chiral amplification or deracemization of these supramolecular fibers.
The Royal Society of Chemistry
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