Mixed halide bulk perovskite triplet sensitizers: Interplay between band alignment, mid-gap traps, and phonons

AS Bieber, ZA VanOrman, HK Drozdick… - The Journal of …, 2021 - pubs.aip.org
Photon upconversion, particularly via triplet–triplet annihilation (TTA), could prove beneficial
in expanding the efficiencies and overall impacts of optoelectronic devices across a
multitude of technologies. The recent development of bulk metal halide perovskites as triplet
sensitizers is one potential step toward the industrialization of upconversion-enabled
devices. Here, we investigate the impact of varying additions of bromide into a lead iodide
perovskite thin film on the TTA upconversion process in the annihilator molecule rubrene …
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