Mononuclear Lanthanide Single Molecule Magnets Based on the Polyoxometalates [Ln(W5O18)2]9− and [Ln2-SiW11O39)2]13−(LnIII = Tb, Dy, Ho, Er …

MA AlDamen, S Cardona-Serra… - Inorganic …, 2009 - ACS Publications
… Here we report the magnetostructural study of two series of mononuclear lanthanide-based
complexes obtained by encapsulation of the lanthanide metal by two monolacunary POM …

Magnetic excitations in polyoxotungstate-supported lanthanoid single-molecule magnets: an inelastic neutron scattering and ab initio study

M Vonci, MJ Giansiracusa, W Van den Heuvel… - Inorganic …, 2017 - ACS Publications
… the crystal field (CF) magnetic excitations of the analogs of the most representative
lanthanoid–polyoxometalate single-molecule magnet family: Na 9 [Ln(W 5 O 18 ) 2 ] (Ln = Nd, Tb, …

Magnetic Polyoxometalates

JM Clemente-Juan, E Coronado… - Polyoxometalate …, 2013 - books.google.com
… In contrast, in the polyoxometalate [Ln (W5O18) 2] 9− the 8 … in this class of mononuclear
lanthanide SMMs at temperatures … In conclusion, the impact of POMs in molecular magnetism is …

Crystal Structure and Magnetic Properties of Peacock–Weakley Type Polyoxometalates Na9[Ln(W5O18)2] (Ln = Tm, Yb): Rare Example of Tm(III) SMM

OY Mariichak, S Kaabel, YA Karpichev… - Magnetochemistry, 2020 - mdpi.com
… 1 is a rare example of a Tm(III)-based single-molecule magnet (… magnetic hysteresis akin
to bulk magnets [1]. The first observation of magnet-like behavior in mononuclear lanthanide

Slow Magnetic Relaxation and Luminescent Properties of Mononuclear Lanthanide-Substituted Keggin-Type Polyoxotungstates with Compartmental Organic Ligands

B Artetxe, E Colacio Rodríguez, L Lezama - 2022 - digibug.ugr.es
… the vacant site of the lacunary polyoxometalate (POM) unit. … of Ln-based compounds is
molecular magnetism. The strong … The high coherence of the [Ho(W5O18)2]9− molecular qubit …

Multi-frequency EPR studies of a mononuclear holmium single-molecule magnet based on the polyoxometalate [Ho III (W 5 O 18) 2] 9−

S Ghosh, S Datta, L Friend, S Cardona-Serra… - Dalton …, 2012 - pubs.rsc.org
… the holmium member of a family of polyoxometalate (POM) complexes, of general formula
[Ln III (W 5 O 18 ) 2 ] 9− , 11,12 in which the lanthanide ion is encapsulated between two W 5 …

[PDF][PDF] Synthesis and characterization of lanthanoid containing polyoxotungstates nanocluster

R Gupta, F Hussain - Trends in Polyoxometalates Research, 2015 - researchgate.net
… Lanthanoids (Ln) ions are of special interest due to the their oxophilicity nature and … .,
reported [Er (W5O18) 2] 9–the first single molecule magnet based on polyoxometalates [10]. Kortz …

Construction of a general library for the rational design of nanomagnets and spin qubits based on mononuclear f-block complexes. The polyoxometalate case

JJ Baldovi, JM Clemente-Juan, E Coronado… - Inorganic …, 2014 - ACS Publications
molecular magnetism has been rejuvenated with the discovery that some mononuclear f-element
complexes display a single… decided to study the magnetic properties of the [Ln(W 5 O …

Theoretical study of systems with interest in molecular magnetism and electronics

S Cardona Serra - 2013 - roderic.uv.es
… was the second one after Ishikawa’s molecules and the one that effectively … “Mononuclear
Lanthanide Single Molecule Magnets Based on the Polyoxometalates [Ln(W5O18)2]9- and [Ln

Theoretical study of systems with interest in molecular magnetism and electronics

SC Serra - 2013 - dialnet.unirioja.es
… was the second one after Ishikawa’s molecules and the one that effectively … “Mononuclear
Lanthanide Single Molecule Magnets Based on the Polyoxometalates [Ln(W5O18)2]9- and [Ln