NHC/Iron cooperative catalysis: aerobic oxidative esterification of aldehydes with phenols

RS Reddy, JN Rosa, LF Veiros, S Caddick… - Organic & Biomolecular …, 2011 - pubs.rsc.org
RS Reddy, JN Rosa, LF Veiros, S Caddick, PMP Gois
Organic & Biomolecular Chemistry, 2011pubs.rsc.org
… An NHC/iron cooperative catalytic system mediates the aerobic oxidative esterification of
aldehydes with phenols. The use of equimolar amounts of reactants led to good to excellent
isolated yields of esters. … Therefore, we initiated a study to establish the direct oxidative
esterification of aldehydes with phenols, catalyzed by a NHC/iron system using atmospheric
O 2 as the terminal oxidant. …
An NHC/iron cooperative catalytic system mediates the aerobic oxidative esterification of aldehydes with phenols. The use of equimolar amounts of reactants led to good to excellent isolated yields of esters.
The Royal Society of Chemistry
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