Nano-carbon in a hydrogel matrix for nonlinear optical applications

AL Nikolaeva, AY Vlasov, IM Kislyakov, VY Elokhovskiy… - Optical Materials, 2017 - Elsevier
AL Nikolaeva, AY Vlasov, IM Kislyakov, VY Elokhovskiy, IM Zorin, SA Povarov
Optical Materials, 2017Elsevier
We report on the optical power limiting properties of nano-sized carbon (single walled
carbon nanotubes and carbon black) embedded in an aqueous-polymer matrix in the phase
state of a hydro-gel. A polymer employed is Pluronic F-127, who simultaneously features as
a stabilizer of the nano-carbon in a fluid water-polymer medium. Limiting thresholds of the
composites are given in a bijection with a phase diagram (determined by DSC, rheometry
and vibrational viscometry) of a matrix alongside its viscous characteristics and caloric …
Abstract
We report on the optical power limiting properties of nano-sized carbon (single walled carbon nanotubes and carbon black) embedded in an aqueous-polymer matrix in the phase state of a hydro-gel. A polymer employed is Pluronic F-127, who simultaneously features as a stabilizer of the nano-carbon in a fluid water-polymer medium. Limiting thresholds of the composites are given in a bijection with a phase diagram (determined by DSC, rheometry and vibrational viscometry) of a matrix alongside its viscous characteristics and caloric properties of phase transitions involving the gel and micellar solution. Reversible gel-to-isotropic fluid transition of the matrix renders optical material thermo-healing with regard to optical breakdowns inflicted by high-intensity laser irradiation in the solid-like gel state.
Elsevier
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