Nanocrystallization and optical properties of CsPbBr3− xIx perovskites in chalcogenide glasses

N Long, Y Fu, T Xu, D Ding, S Zhang, S Sun… - Journal of the European …, 2021 - Elsevier
N Long, Y Fu, T Xu, D Ding, S Zhang, S Sun, S Kang, T Xu, S Dai, Q Nie, C Lin
Journal of the European Ceramic Society, 2021Elsevier
The confinement of CsPbX 3 (X= Cl, Br, and I) perovskite nanocrystals (NCs) in a stabilized
inorganic glass matrix is a new strategy for improving their long-term stability and promoting
their applications in the optoelectronic field. Here, in situ nanocrystallization strategy is
developed to precipitate CsPbBr 3− x I x NCs with arbitrary I/Br ratio among an elaborately
designed GeS 2–Sb 2 S 3-based chalcogenide glass matrix. Spherical CsPbBr 3− x I x NCs
are homogeneously distributed in the glass matrix after thermal treatment. The …
Abstract
The confinement of CsPbX3 (X = Cl, Br, and I) perovskite nanocrystals (NCs) in a stabilized inorganic glass matrix is a new strategy for improving their long-term stability and promoting their applications in the optoelectronic field. Here, in situ nanocrystallization strategy is developed to precipitate CsPbBr3−xIx NCs with arbitrary I/Br ratio among an elaborately designed GeS2–Sb2S3-based chalcogenide glass matrix. Spherical CsPbBr3−xIx NCs are homogeneously distributed in the glass matrix after thermal treatment. The photoluminescence (PL) spectra show that the emission peaks of CsPbBr3−xIx NCs can be tuned from 570 nm to 722 nm with the replacement of Br by I. The fs transient absorption (TA) spectra reveal that there exists some structural defects in the NCs, leading to short PL decay life. This work would shed light on confining CsPbX3 NCs into glassy matrices, facilitating their future applications in photoelectronic fields.
Elsevier
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