New nitrosyl ruthenium complex [RuCl (NO)(dcype)(bipy)](PF6) 2: Synthesis, electrochemistry, NMR and ESI-MS/MS studies
Reactivity of cis-[RuCl2 (dcype)(bipy)](dcype= 1, 2-bis (dicyclohexylphosphino) ethane and
bipy= 2, 2′-bipyridine) with nitric oxide afforded the new dicationic complex [RuCl
(NO)(dcype)(bipy)] 2+. The complex isolated as PF6-salt was characterized by
spectroscopical, electrochemical and ESI-MS/MS techniques as well as elemental analysis.
Surprisingly the analysis of 31P {1H} and 15N {1H} NMR spectra of the [RuCl
(15NO)(dcype)(bipy)] 2+ complex reveal that the NO is in trans position to one of the P atom …
bipy= 2, 2′-bipyridine) with nitric oxide afforded the new dicationic complex [RuCl
(NO)(dcype)(bipy)] 2+. The complex isolated as PF6-salt was characterized by
spectroscopical, electrochemical and ESI-MS/MS techniques as well as elemental analysis.
Surprisingly the analysis of 31P {1H} and 15N {1H} NMR spectra of the [RuCl
(15NO)(dcype)(bipy)] 2+ complex reveal that the NO is in trans position to one of the P atom …
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