Non-isothermal sintering with concurrent crystallization of polydispersed soda–lime–silica glass beads

MO Prado, C Fredericci, ED Zanotto - Journal of Non-Crystalline Solids, 2003 - Elsevier
MO Prado, C Fredericci, ED Zanotto
Journal of Non-Crystalline Solids, 2003Elsevier
We test the Clusters model for non-isothermal sintering of crystallizing polydispersed
particles against experimental data obtained under different conditions. We demonstrate that
the model predicts the densification curves for two distinct size distributions of devitrifying
soda–lime–silica glass having spherical particles. For each system a minimum heating rate
can be found, so that for higher rates the compacts always reach maximum density, while for
lower heating rates crystallization inhibits densification. In the latter case, the residual …
We test the Clusters model for non-isothermal sintering of crystallizing polydispersed particles against experimental data obtained under different conditions. We demonstrate that the model predicts the densification curves for two distinct size distributions of devitrifying soda–lime–silica glass having spherical particles. For each system a minimum heating rate can be found, so that for higher rates the compacts always reach maximum density, while for lower heating rates crystallization inhibits densification. In the latter case, the residual porosity increases with decreasing heating rate. We discuss the results taking into account several complicating factors, such as pre-existing surface crystals, the average number of necks per particle, compositional shifts due to crystallization, temperature gradients and degassing during sintering. Finally, we discuss the physical and processing parameters that determine whether sintering will be favorable over crystallization.
Elsevier
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