On the incidence of non-covalent intramolecular interligand interactions on the conformation of carbene complexes: a case study
N Lugan, I Fernández, R Brousses, DA Valyaev… - Dalton …, 2013 - pubs.rsc.org
N Lugan, I Fernández, R Brousses, DA Valyaev, G Lavigne, NA Ustynyuk
Dalton Transactions, 2013•pubs.rsc.orgThe prevalence of a counterintuitive carbene conformation in a series of piano-stool Mn (I)
alkylalkoxycarbene complexes was rationalized by means of DFT calculations and high-
resolution XRD analysis in terms of stabilizing non-covalent C–H⋯ CO interligand
interactions.
alkylalkoxycarbene complexes was rationalized by means of DFT calculations and high-
resolution XRD analysis in terms of stabilizing non-covalent C–H⋯ CO interligand
interactions.
The prevalence of a counterintuitive carbene conformation in a series of piano-stool Mn(I) alkylalkoxycarbene complexes was rationalized by means of DFT calculations and high-resolution XRD analysis in terms of stabilizing non-covalent C–H⋯CO interligand interactions.
The Royal Society of Chemistry