Optimization of Synthesis Parameters and Superconducting Properties of GdFeAsO1-xFx

M Azam, M Manasa, T Zajarniuk… - IEEE Transactions …, 2023 - ieeexplore.ieee.org
M Azam, M Manasa, T Zajarniuk, S Stelmakh, T Cetner, A Morawski, A Wiśniewski, SJ Singh
IEEE Transactions on Applied Superconductivity, 2023ieeexplore.ieee.org
RE FeAsO (RE 1111; RE: rare earth) belongs to the 1111 family of iron-based
superconductors (FBS), which illustrates the enhancement of the superconducting transition
(T c) with smaller radii of RE. However, the synthesis of the 1111 phase with a heavy rare-
earth is always challenging. In this paper, we report the optimization of the growth and
superconducting properties of F-doped GdFeAsO 1-x F x bulks by preparing the samples in
a wide temperature range (700–1100° C) at ambient pressure. The optimized synthesis …
RE FeAsO ( RE 1111; RE : rare earth) belongs to the 1111 family of iron-based superconductors (FBS), which illustrates the enhancement of the superconducting transition ( Tc ) with smaller radii of RE . However, the synthesis of the 1111 phase with a heavy rare-earth is always challenging. In this paper, we report the optimization of the growth and superconducting properties of F-doped GdFeAsO 1- x F x bulks by preparing the samples in a wide temperature range (700–1100 °C) at ambient pressure. The optimized synthesis parameters are concluded based on structural, microstructural, transport, and magnetic measurements. These findings suggest that the optimal conditions for preparing F-doped Gd1111 bulks involve a two-step process at 900 °C for 61 hours at ambient pressure, which is lower than previously reported. The optimized samples have revealed the superconducting transition temperature ( Tconset ) of 43 K for GdFeAsO 0.83 F 0.17 . The first-time reported critical current Jc value for this Gd1111 is observed of the order of 10 3 A/cm 2 at 0 T and 5 K. Our investigation also concluded that highly pure precursors, particularly gadolinium metal, are required to achieve the superconducting properties of F-doped Gd1111. A high growth pressure of 1 GPa reduces the superconducting properties of F-doped Gd1111.
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