[HTML][HTML] Orthorhombic Ta3-xN5-yOy thin films grown by unbalanced magnetron sputtering: The role of oxygen on structure, composition, and optical properties

JC Chang, F Eriksson, MA Sortica, G Greczynski… - Surface and Coatings …, 2021 - Elsevier
Surface and Coatings Technology, 2021Elsevier
Direct growth of orthorhombic Ta 3 N 5-type Ta-ON compound thin films, specifically Ta 3-x
N 5-y O y, on Si and sapphire substrates with various atomic fractions is realized by
unbalanced magnetron sputtering. Low-degree fiber-textural Ta 3-x N 5-y O y films were
grown through reactive sputtering of Ta in a gas mixture of N 2, Ar, and O 2 with keeping a
partial pressure ratio of 3: 2: 0.1 in a total working pressure range of 5–30 mTorr. With
increasing total pressure from 5 to 30 mTorr, the atomic fraction of O in the as-grown Ta 3-x …
Abstract
Direct growth of orthorhombic Ta3N5-type Ta-O-N compound thin films, specifically Ta3-xN5-yOy, on Si and sapphire substrates with various atomic fractions is realized by unbalanced magnetron sputtering. Low-degree fiber-textural Ta3-xN5-yOy films were grown through reactive sputtering of Ta in a gas mixture of N2, Ar, and O2 with keeping a partial pressure ratio of 3:2:0.1 in a total working pressure range of 5–30 mTorr. With increasing total pressure from 5 to 30 mTorr, the atomic fraction of O in the as-grown Ta3-xN5-yOy films was found to increase from 0.02 to 0.15 while that of N and Ta decrease from 0.66 to 0.54 and 0.33 to 0.31, respectively, leading to a decrease in b lattice constant up to around 1.3%. Metallic TaNx phases were formed without oxygen. For a working pressure of 40 mTorr, an amorphous, O-rich Ta-N-O compound film with a high O fraction of ~0.48, was formed, mixed with non-stoichiometric TaON and Ta2O5. By analyzing the plasma discharge, the increasing O incorporation is associated with oxide formation on top of the Ta target due to a higher reactivity of Ta with O than with N. The increase of O incorporation in the films also leads to a bandgap widening from ~2.22 to ~2.96 eV, which is in agreement with the structural change from a crystalline Ta3-xN5-yOy to an amorphous O-rich Ta-O-N compound.
Elsevier
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