Oxidation of organic molecules in homogeneous aqueous solution catalyzed by hybrid biocatalysts (based on the Trojan Horse strategy)
New anionic metalloporphyrin–estradiol conjugates have been synthesized and fully
characterized, and have been further associated to a monoclonal anti-estradiol antibody
7A3, to generate new artificial metalloenzymes following the so-called 'Trojan
Horse'strategy. The spectroscopic characteristics and dissociation constants of these
complexes were similar to those obtained for the artificial metalloproteins obtained by
association of cationic metalloporphyrin–estradiol conjugates to 7A3. This demonstrates that …
characterized, and have been further associated to a monoclonal anti-estradiol antibody
7A3, to generate new artificial metalloenzymes following the so-called 'Trojan
Horse'strategy. The spectroscopic characteristics and dissociation constants of these
complexes were similar to those obtained for the artificial metalloproteins obtained by
association of cationic metalloporphyrin–estradiol conjugates to 7A3. This demonstrates that …
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