Palladium-catalyzed asymmetric α-arylation of alkylnitriles
Asymmetric arylation of alkylnitriles forms quaternary stereocenters in good enantiocontrol
for the first time. A lithium heterodimer consisting of an alkylnitrile anion and a disilylamide
ion is the actual species responsible for the stereodetermining transmetalation in the
catalytic cycle.
for the first time. A lithium heterodimer consisting of an alkylnitrile anion and a disilylamide
ion is the actual species responsible for the stereodetermining transmetalation in the
catalytic cycle.
[引用][C] Palladium-Catalyzed Asymmetric α-Arylation of Alkylnitriles
J Zhiwei, CK Wei, Z Jianrong - 2016
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