Partial coalescence of drops at liquid interfaces

F Blanchette, TP Bigioni - Nature Physics, 2006 - nature.com
F Blanchette, TP Bigioni
Nature Physics, 2006nature.com
When two separate masses of the same fluid are brought gently into contact, they are
expected to fully merge into a single larger mass to minimize surface energy. However,
when a stationary drop coalesces with an underlying reservoir of identical fluid, merging
does not always proceed to completion. Occasionally, a drop in the process of merging
apparently defies surface tension by 'pinching off'before total coalescence occurs, leaving
behind a smaller daughter droplet,,. Moreover, this process can repeat itself for subsequent …
Abstract
When two separate masses of the same fluid are brought gently into contact, they are expected to fully merge into a single larger mass to minimize surface energy. However, when a stationary drop coalesces with an underlying reservoir of identical fluid, merging does not always proceed to completion. Occasionally, a drop in the process of merging apparently defies surface tension by ‘pinching off’ before total coalescence occurs, leaving behind a smaller daughter droplet,,. Moreover, this process can repeat itself for subsequent generations of daughter droplets, resulting in a cascade of self-similar events. Such partial coalescence behaviour has implications for the dynamics of a variety of systems, including the droplets in clouds, ocean mist and airborne salt particles, emulsions, and the generation of vortices near an interface,. Although it was first observed almost half a century ago, little is known about its precise mechanism. Here, we combine high-speed video imaging with numerical simulations to determine the conditions under which partial coalescence occurs, and to reveal a dynamic pinch-off mechanism. This mechanism is critically dependent on the ability of capillary waves to vertically stretch the drop by focusing energy on its summit.
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