Phase Diagrams of Fullerenol-d–LaCl3–H2O and Fullerenol-d–GdCl3–H2O Systems at 25°С

VA Keskinov, KN Semenov, TS Gol'tsov… - Russian Journal of …, 2019 - Springer
VA Keskinov, KN Semenov, TS Gol'tsov, NA Charykov, NE Podol'skii, AV Kurilenko…
Russian Journal of Physical Chemistry A, 2019Springer
Isothermal phase diagrams of ternary systems fullerenol-d–LaCl 3–H 2 O and fullerenol-d–
GdCl 3–H 2 O at 25° C are studied via saturation technique. Solubility diagrams are found to
be of a simple eutonic type and are characterized by the salting-out of chloride upon adding
fullerenol-d, and short branches of LaCl 3· 7H 2 O and GdCl 3· 6H 2 O crystallization, where
the salting-in effect is observed.
Abstract
Isothermal phase diagrams of ternary systems fullerenol-d–LaCl3–H2O and fullerenol-d–GdCl3–H2O at 25°C are studied via saturation technique. Solubility diagrams are found to be of a simple eutonic type and are characterized by the salting-out of chloride upon adding fullerenol-d, and short branches of LaCl3 · 7H2O and GdCl3 · 6H2O crystallization, where the salting-in effect is observed.
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