Phenylamino derivatives of tris (2-pyridylmethyl) amine: hydrogen-bonded peroxodicopper complexes
EW Dahl, HT Dong, NK Szymczak - Chemical Communications, 2018 - pubs.rsc.org
EW Dahl, HT Dong, NK Szymczak
Chemical Communications, 2018•pubs.rsc.orgA series of copper complexes bearing new 6-substituted tris (2-pyridylmethyl) amine ligands
(LR) appended with NH (pR-C6H4) groups (R= H, CF3, OMe) were prepared. These ligands
are electronically tunable (ΔE1/2= 160 mV) and CuI (LR)+ complexes react with oxygen to
form hydrogen bonded (trans-1, 2-peroxo) dicopper species.
(LR) appended with NH (pR-C6H4) groups (R= H, CF3, OMe) were prepared. These ligands
are electronically tunable (ΔE1/2= 160 mV) and CuI (LR)+ complexes react with oxygen to
form hydrogen bonded (trans-1, 2-peroxo) dicopper species.
A series of copper complexes bearing new 6-substituted tris(2-pyridylmethyl)amine ligands (LR) appended with NH(p-R-C6H4) groups (R = H, CF3, OMe) were prepared. These ligands are electronically tunable (ΔE1/2 = 160 mV) and CuI(LR)+ complexes react with oxygen to form hydrogen bonded (trans-1,2-peroxo)dicopper species.
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