(two-dimensional) and tubular (one-dimensional) oxides and suboxides, most of them
insulating. This confers to black phosphorus a native oxide that can be used as barrier
material and protective layer. Furthermore, the bandgap of phosphorene oxides depends on
the oxygen concentration, suggesting that controlled oxidation can be used as a means to
engineer the bandgap. For the oxygen saturated composition, P 2 O 5, both the planar and …