Photodesorption of NO from a metal surface: quantum dynamical implications of a two-mode model
P Saalfrank, G Boendgen, K Finger, L Pesce - Chemical Physics, 2000 - Elsevier
Open-system density matrix theory is used to study the dissipative quantum dynamics of
photoinduced, hot-electron mediated desorption of NO from Pt (111). Two electronic states
are considered and both the DIET (Desorption Induced by Electronic Transitions) and
DIMET (Desorption Induced by Multiple Electronic Transitions) limits addressed. Besides the
center-of-mass motion of the molecule perpendicular to the surface plane, the vibrational
motion of the NO molecule is accounted for. In a first, methodological part the interrelations …
photoinduced, hot-electron mediated desorption of NO from Pt (111). Two electronic states
are considered and both the DIET (Desorption Induced by Electronic Transitions) and
DIMET (Desorption Induced by Multiple Electronic Transitions) limits addressed. Besides the
center-of-mass motion of the molecule perpendicular to the surface plane, the vibrational
motion of the NO molecule is accounted for. In a first, methodological part the interrelations …
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