Platinum diimine-dithiolate complexes as a new class of photoconducting compounds for pristine photodetectors: case study on [Pt (bipy)(Naph-edt)](bipy= 2, 2 …
Dalton Transactions, 2021•pubs.rsc.org
The photoconducting properties of platinum diimine-dithiolate complex [Pt (bipy)(Naph-
edt)](1; bipy= 2, 2′-bipyridine; Naph-edt2−= 2-naphthylethylene-1, 2-dithiolate) were
investigated. DFT calculations on a model assembly with four complex units suggest that the
high external quantum efficency measured on a prototype photodetector correlates with the
intermolecular character of electronic excitations in the visible region.
edt)](1; bipy= 2, 2′-bipyridine; Naph-edt2−= 2-naphthylethylene-1, 2-dithiolate) were
investigated. DFT calculations on a model assembly with four complex units suggest that the
high external quantum efficency measured on a prototype photodetector correlates with the
intermolecular character of electronic excitations in the visible region.
The photoconducting properties of platinum diimine-dithiolate complex [Pt(bipy)(Naph-edt)] (1; bipy = 2,2′-bipyridine; Naph-edt2− = 2-naphthylethylene-1,2-dithiolate) were investigated. DFT calculations on a model assembly with four complex units suggest that the high external quantum efficency measured on a prototype photodetector correlates with the intermolecular character of electronic excitations in the visible region.
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