Polyhydroxycarbosilanes of dendritic structure

EV Getmanova, TB Chenskaya… - Reactive and Functional …, 1997 - Elsevier
Synthesis of a versatile hydroxysilylation agent and its use in the preparation of hydroxy
derivatives of a poly (allylcarbosilane) dendrimer and hyperbranched polymer are reported.
In a first approximation, the bulk properties of synthesized hydroxy polymers are found to
essentially identical. Infrared spectroscopy provides evidence for the build-up of a
complicated H-bond network in these polymers. Spectroscopic study of the hydroxyl groups
can gain a deeper insight into the properties of branched dendrite-core macromolecules.
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