Synthesis of well-defined polymer architectures by successive catalytic olefin polymerization and living/controlled polymerization reactions

RG Lopez, F D'agosto, C Boisson - Progress in polymer science, 2007 - Elsevier
initiating sites for other successively applied polymerization … polyolefins and hydrophilic
functional polymers such as poly(ε-… The B–H groups in these boranes are very reactive toward …

Recent developments in the synthesis of functional poly (olefin) s

MJ Yanjarappa, S Sivaram - Progress in polymer science, 2002 - Elsevier
… as lack of reactive functional groups in the polymer structure … or compatibility with other
functional polymers is paramount. … polymeric alkoxy radicals are highly reactive and initiate the …

Design and synthesis of structurally well-defined functional polyolefins via transition metal-mediated olefin polymerization chemistry

JY Dong, Y Hu - Coordination Chemistry Reviews, 2006 - Elsevier
… The benzylic proton in the p-MS units is very reactive and … functional side groups and
functional polymers containing a … bond, which initiated living polymerization of MMA to prepare

FI Catalysts for olefin polymerization A comprehensive treatment

H Makio, H Terao, A Iwashita, T Fujita - Chemical reviews, 2011 - ACS Publications
… to study the mechanisms of the initiation, propagation, and termination steps of coordination
… structure−reactivity relationships in olefin polymerization mediated by these catalysts. …

Precision control of radical polymerization via transition metal catalysis: from dormant species to designed catalysts for precision functional polymers

M Ouchi, T Terashima, M Sawamoto - Accounts of chemical …, 2008 - ACS Publications
polymerization, with alkyl vinyl ethers as monomers, initiated … of the nonconjugating and
highly reactive VAc growing radical … Rather surprisingly, though hydrocarbon olefins have long …

Synthesis of functional polyolefin copolymers with graft and block structures

TC Chung - Progress in polymer science, 2002 - Elsevier
… In other words, we could treat the borane monomer as a high α-olefin in the … The alkoxyl
radical (C–O∗) is very reactive and can then be used for the initiation of radical polymerization

Catalysts for the living insertion polymerization of alkenes: access to new polyolefin architectures using Ziegler–Natta chemistry

GW Coates, PD Hustad… - Angewandte Chemie …, 2002 - Wiley Online Library
methods also allow the synthesis of end-functional polymers if special initiation and/or quenching
methods … therefore include all systems that claim living olefin polymerization, providing …

Synthesis of polyolefin block and graft copolymers

MAJ SCHELLEKENS… - … Science, Part C: Polymer …, 2000 - Taylor & Francis
… can be activated to initiate polymerization of a second monomer… cyclic olefin, the product is
a linear ring-opened polymer with … a very reactive alkoxy radical (C─O·) (2), which can initiate

[图书][B] Functionalization of polyolefins

TC Chung - 2002 - books.google.com
… The low cost of olefin monomers and extremely high polymer/… that the most direct route to
prepare functional polymers is … Usually, the reaction was initiated by charging the catalyst …

Catalytic polymerization and post polymerization catalysis fifty years after the discovery of Ziegler's catalysts

R Mülhaupt - Macromolecular Chemistry and Physics, 2003 - Wiley Online Library
systems and Natta's stereoselective olefin polymerization set … traces of oxygen initiated the
free radical polymerization. Due to … highly reactive with respect to the incorporation of higher 1-…