Potassium permanganate, a versatile reagent for the aromatization of Hantzsch 1, 4-dihydropyridines

JJV Eynde, R D'Orazio, Y Van Haverbeke - Tetrahedron, 1994 - Elsevier
… Thus, our results reveal that aromatization of a 4-n-alQ+1,4dihydropyridine in the prsence of
potassium permanganate can occur following two competitive mechanisms depending on the
experimental conditions: the expected ionic pathway13 yields 2 whereas a radical pathway
yields 3. For the other derivatives (R’ = benzyl, secondary alkyl, aryl), the competition is not
apparent. This can be rationalixed as foJJows: the ionic pathway proceeds through expulsion …
In conclusion, from a practical point of view, aromatization of Hantxsch 1,4-dihydropyridines by …

[引用][C] Potassium permanganate, a versatile reagent for the aromatization of Hantzsch 1, 4-dihydropyridines

JJ Vanden Eynde, R D'orazio… - Tetrahedron (Oxford …, 1994 - pascal-francis.inist.fr
Potassium permanganate, a versatile reagent for the aromatization of Hantzsch 1,4-dihydropyridines
Potassium permanganate, a versatile reagent for the aromatization of Hantzsch 1,4-dihydropyridines
Potassium Permanganates …
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