Preparative synthesis of vinyl diamondoids
Synthetic Communications, 2013•Taylor & Francis
We describe a convenient four-step preparation of 1-vinyl adamantane, 1-vinyl diamantane,
and 4, 9-divinyl diamantane from the respective diamondoid acetic acids in 50–80% isolated
yields involving esterification, reduction, and hydrobromination/dehydrobromination.
Supplemental materials are available for this article. Go to the publisher's online edition of
Synthetic Communications® to view the free supplemental file.
and 4, 9-divinyl diamantane from the respective diamondoid acetic acids in 50–80% isolated
yields involving esterification, reduction, and hydrobromination/dehydrobromination.
Supplemental materials are available for this article. Go to the publisher's online edition of
Synthetic Communications® to view the free supplemental file.
Abstract
We describe a convenient four-step preparation of 1- vinyl adamantane, 1- vinyl diamantane, and 4,9-divinyl diamantane from the respective diamondoid acetic acids in 50–80% isolated yields involving esterification, reduction, and hydrobromination/dehydrobromination.
Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications® to view the free supplemental file.
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