… -Hydroxymethylfurfural (5-HMF) production from hexoses: limits of heterogeneous catalysis in hydrothermal conditions and potential of concentrated aqueous organic …

RL De Souza, H Yu, F Rataboul, N Essayem - Challenges, 2012 - mdpi.com
preparation of 5-hydroxymethylfurfural with the influence of a large panel of solid catalysts in
pure hydrothermal conditions using fructosesingle phase, free of 5-MHF extractive solvent. …

Sugaring‐out assisted organic-aqueous biphasic systems: Characteristics, mechanisms and applications

R Sadeghi, JAP Coutinho - Separation and Purification Technology, 2024 - Elsevier
produce three types of ABSs: organic solvent-sugar, polymer-sugar, and IL-sugar ABSs that
have been formed from the sugaring-out of aqueous organic … a clear single-phase system. In …

Solvent selection for biphasic extraction of 5-hydroxymethylfurfural via multiscale modeling and experiments

Z Wang, S Bhattacharyya, DG Vlachos - Green Chemistry, 2020 - pubs.rsc.org
… solvent selection framework for aqueousorganic reactive extraction using the multiscale
COSMO… We apply the model to HMF produced in acid-catalyzed dehydration of fructose. Model …

Synthesis of 5-hydroxymethylfurfural (HMF) by acid catalyzed dehydration of glucose–fructose mixtures

AT Pedersen, R Ringborg, T Grotkjær… - Chemical Engineering …, 2015 - Elsevier
… to fructose would allow cheap production of HMF. The isomerization of glucose to fructose
is … while maintaining a single phase at the fructose and glucose concentrations investigated. …

Conversion of Glucose to 5-Hydroxymethylfurfural in a Microreactor

T Tongtummachat, N Akkarawatkhoosith… - Frontiers in …, 2020 - frontiersin.org
… than that obtained from the single phase system. The superior 5-HMF production in our system
in … involves the isomerization of glucose to fructose and dehydration of fructose to 5-HMF, …

Extraction of furfural and furfural/5-hydroxymethylfurfural from mixed lignocellulosic biomass-derived feedstocks

Z Wang, S Bhattacharyya… - … Sustainable Chemistry & …, 2021 - ACS Publications
… and 5-hydroxymethylfurfural (HMF) in aqueousorganic … vial, and diluted with acetonitrile
to restore the single phase. … Fructose does not partition substantially to the organic phase, …

Understanding and Enhancing the Catalytic Production of 5-Hydroxymethylfurfural from Fructose in Aqueous Cosolvent Systems

G Svenningsen - 2018 - escholarship.org
… the conversion of HMF to DMF in a single-phase solution by functionalizing bimetallic …
selectivity to HMF from fructose using either a homogeneous or heterogeneous acid. …

5hydroxymethylfurfural and its Downstream Chemicals: A Review of Catalytic Routes

C Chen, M Lv, H Hu, L Huai, B Zhu, S Fan… - Advanced …, 2024 - Wiley Online Library
production from high-concentration fructose.[28] Our group reported the sulfoxide compound
diphenyl sulfoxide (DPhSO) as both catalyst and solvent for fructose … both single-phase and …

Catalytic Conversion of Cellulose to 5Hydroxymethylfurfural: Advancements in Heterogeneous Catalysts and Cutting‐Edge Hydrolysis Strategies

A Rezayan, Y Zhang, B Li, CC Xu - ChemCatChem, 2023 - Wiley Online Library
producing glucose using a Bronsted acid catalyst, followed by an isomerization reaction to
convert glucose into fructose using … excessive NMP formed a single-phase reaction system, …

Experimental and modelling studies on the synthesis of 5-hydroxymethylfurfural from sugars

RJ van Putten - 2015 - research.rug.nl
… of various solvent systems, and on the different production routes reported in the last decade…
and aqueous/organic single-phase mixtures. Fructose dehydration in water based systems …